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The reorientation dynamics of local tangent vectors of chains in isotropic amorphous melts containing semiflexible model polymers was studied by molecular dynamics simulations. The reorientation is strongly influenced both by the local…

Soft Condensed Matter · Physics 2016-08-15 Roland Faller , Florian Müller-Plathe , Andreas Heuer

The persistence length of macromolecules is one of their basic characteristics, describing their intrinsic local stiffness. However, it is difficult to extract this length from physical properties of the polymers, different recipes may give…

Soft Condensed Matter · Physics 2013-03-12 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

Using a transfer matrix technique, we calculate the entropy of polydisperse chains placed on a one-dimensional lattice, as a function of the density of internal and endpoint monomers. The polydispersivity is determined considering different…

Statistical Mechanics · Physics 2009-11-11 Jurgen F. Stilck , Minos A. Neta , Wellington G. Dantas

Single linear polymer chains in dilute solutions under good solvent conditions are studied by Monte Carlo simulations with the pruned-enriched Rosenbluth method up to the chain length $N \sim {\cal O}(10^4)$. Based on the standard simple…

Soft Condensed Matter · Physics 2015-06-24 Hsiao-Ping Hsu

We systematically explore the self-assembly of semi-flexible polymers in deformable spherical confinement across a wide regime of chain stiffness, contour lengths and packing fractions by means of coarse-grained molecular dynamics…

Soft Condensed Matter · Physics 2021-07-12 Maxime M. C. Tortora , Daniel Jost

In the first part of this work the classical and statistical aspects of the dynamics of an inextensible chain in three dimensions are investigated. In the second part the special case of a chain admitting only fixed angles with respect to…

Statistical Mechanics · Physics 2009-05-22 Franco Ferrari , Jaroslaw Paturej , Thomas A. Vilgis

The endpoint distribution and dynamics of semiflexible fibers is studied by numerical simulation. A brief overview is given over the analytical theory of flexible and semiflexible polymers. In particular, a closed expression is given for…

Soft Condensed Matter · Physics 2013-06-13 Robert D. Groot

We present a unifying picture of the compact, dense and dilute phases of two-dimensional polymers. The lattice dependence of the scaling exponents for compact polymers is reconciled with their universality in the dense and dilute case. In…

Statistical Mechanics · Physics 2007-05-23 Jesper Lykke Jacobsen , Jane' Kondev

A simple model of a circularly closed dsDNA in a poor solvent is considered as an example of a semi-flexible polymer with self-attraction. To find the ground states, the conformational energy is computed as a sum of the bending and…

Biological Physics · Physics 2013-04-25 E. L. Starostin

We study a kinetically constrained lattice glass model in which continuous local densities are randomly redistributed on neighbouring sites with a kinetic constraint that inhibits the process at high densities, and a random bias accounting…

Disordered Systems and Neural Networks · Physics 2007-05-23 Eric Bertin , Jean-Philippe Bouchaud , Francois Lequeux

The effect of ring stiffness and pressure on the glassy dynamics of a thermal assembly of two-dimensional ring polymers is investigated using extensive coarse-grained molecular dynamics simulations. In all cases, dynamical slowing down is…

Soft Condensed Matter · Physics 2023-06-06 Sayantan Ghosh , Satyavani Vemparala , Pinaki Chaudhuri

We consider the escape of a flexible, self-avoiding polymer chain out of a confined geometry. By means of simulations, we demonstrate that the translocation time can be described by a simple scaling law that exhibits a nonlinear dependence…

Soft Condensed Matter · Physics 2009-11-11 Angelo Cacciuto , Erik Luijten

The Langevin Equation for cooperative dynamics represents the dynamics of polymer melts with chains of increasing degree of polymerization, covering the full range of behavior from the unentangled to the entangled regime. This equation…

Soft Condensed Matter · Physics 2015-09-30 M. G. Guenza

Two ring polymers close to each other in space may be either in a segregated phase if there is a strong repulsion between monomers in the polymers, or intermingle in a mixed phase if there is a strong attractive force between the monomers.…

Soft Condensed Matter · Physics 2022-11-23 EJ Janse van Rensburg , E Orlandini , MC Tesi , SG Whittington

We develop a statistical theory for the dynamics of non-aligning, non-interacting self-propelled particles confined in a convex box in two dimensions. We find that when the size of the box is small compared to the persistence length of a…

Soft Condensed Matter · Physics 2014-08-05 Yaouen Fily , Aparna Baskaran , Michael F. Hagan

We explore the critical behaviour of two and three dimensional lattice models of polymers in dilute solution where the monomers carry a magnetic moment which interacts ferromagnetically with near-neighbour monomers. Specifically, the model…

Statistical Mechanics · Physics 2021-08-25 Damien Paul Foster , Debjyoti Majumdar

We present the results of analytic calculations and numerical simulations of the behaviour of a new class of chain molecules which we call thick polymers. The concept of the thickness of such a polymer, viewed as a tube, is encapsulated by…

Soft Condensed Matter · Physics 2015-06-25 D. Marenduzzo , A. Flammini , A. Trovato , J. R. Banavar , A. Maritan

The vibrational dynamics of a model polymer glass is studied by Molecular Dynamics simulations. The focus is on the "soft" monomers with high participation to the lower-frequency vibrational modes contributing to the thermodynamic anomalies…

Soft Condensed Matter · Physics 2021-04-22 Carlo Andrea Massa , Francesco Puosi , Antonio Tripodo , Dino Leporini

We consider a model of an extensible semiflexible filament moving in two dimensions on a motility assay of motor proteins represented explicitly as active harmonic linkers. Their heads bind stochastically to polymer segments within a…

Biological Physics · Physics 2021-08-31 Amir Shee , Nisha Gupta , Abhishek Chaudhuri , Debasish Chaudhuri

Reptation governs motion of long polymers through a confining environment. Slack enters at the ends and diffuses along the polymer as stored length. The rate at which stored length diffuses limits the speed at which the chain can drift.…

Soft Condensed Matter · Physics 2015-06-25 M. Widom , I. Al-Lehyani