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For binary fluid mixtures of spherical particles in which the two species are sufficiently different in size, the dominant wavelength of oscillations of the pair correlation functions is predicted to change from roughly the diameter of the…

Statistical Mechanics · Physics 2016-05-04 Antonia Statt , Rattachai Pinchaipat , Francesco Turci , Robert Evans , C. Patrick Royall

We study various manifestations of structural crossover in the properties of a binary mixture of hard-spheres. For homogeneous mixtures that are sufficiently asymmetric, there is a crossover line in the phase diagram such that for…

Soft Condensed Matter · Physics 2009-11-11 C. Grodon , M. Dijkstra , R. Evans , R. Roth

The structural properties of additive binary hard-sphere mixtures are addressed as a follow-up of a previous paper [S. Pieprzyk et al., Phys. Rev. E 101, 012117 (2020)]. The so-called rational-function approximation method and an approach…

Using computed x-ray tomography we determine the three dimensional (3d) structure of binary hard sphere mixtures as a function of composition and size ratio of the particles, q. Using a recently introduced four-point correlation function we…

Soft Condensed Matter · Physics 2023-02-15 Houfei Yuan , Zhen Zhang , Walter Kob , Yujie Wang

We examine the structural and dynamic properties of confined binary hard-sphere mixtures designed to mimic realizable colloidal thin films. Using computer simulations, governed by either Newtonian or overdamped Langevin dynamics, together…

Soft Condensed Matter · Physics 2015-05-01 Jonathan A. Bollinger , Avni Jain , James Carmer , Thomas M. Truskett

A theoretical study of the structure formation observed very recently [Phys. Rev. Lett. 90, 128303 (2003)] in binary colloids is presented. In our model solely the dipole-dipole interaction of the particles is considered,…

Soft Condensed Matter · Physics 2009-11-10 Imre Varga , Ferenc Kun , Karoly F. Pal

We identify putative load-bearing structures (bridges) in experimental colloidal systems studied by confocal microscopy. Bridges are co-operative structures that have been used to explain stability and inhomogeneous force transmission in…

Soft Condensed Matter · Physics 2010-06-18 Matthew C. Jenkins , Mark D. Haw , Gary C. Barker , Wilson C. K. Poon , Stefan U. Egelhaaf

We explore structural correlations of strongly asymmetric mixtures of binary charged colloids within the primitive model of electrolytes considering large charge and size ratios of 10 and higher. Using computer simulations with explicit…

Soft Condensed Matter · Physics 2022-07-13 Elshad Allahyarov , Hartmut Löwen , Alan Denton

We combine experiments and simulations to study the link between criticality and gelation in sticky spheres. We employ confocal microscopy to image colloid-polymer mixtures, and Monte Carlo simulations of the square-well (SW) potential as a…

Soft Condensed Matter · Physics 2018-08-17 David Richard , James Hallett , Thomas Speck , C. Patrick Royall

We examine binary mixtures of superparamagnetic colloidal particles confined to a two-dimensional water-air interface both by real-space experiments and Monte-Carlo computer simulations at high coupling strength. In the simulations, the…

Soft Condensed Matter · Physics 2015-05-13 L Assoud , F Ebert , P Keim , R Messina , G Maret , H Löwen

We use discontinuous molecular dynamics and grand-canonical transition-matrix Monte Carlo simulations to explore how confinement between parallel hard walls modifies the relationships between packing fraction, self-diffusivity, partial…

Soft Condensed Matter · Physics 2009-11-13 Jeetain Mittal , Vincent K. Shen , Jeffrey R. Errington , Thomas M. Truskett

We study the influence of composition changes on the glass transition of binary hard disc and hard sphere mixtures in the framework of mode coupling theory. We derive a general expression for the slope of a glass transition line. Applied to…

Soft Condensed Matter · Physics 2010-09-15 D. Hajnal , J. M. Brader , R. Schilling

In this paper, I relate the phase separation transition in binary hard-core mixtures in the limit of small size ratio to a bond percolation transition. It allows to estimate the critical packing fraction at the transition as a function of…

Statistical Mechanics · Physics 2009-10-31 Arnaud Buhot

The structure and spatial statistical properties of amorphous ellipsoid assemblies have profound scientific and industrial significance in many systems, from cell assays to granular materials. This paper uses a fundamental theoretical…

Soft Condensed Matter · Physics 2026-02-10 F. M. Schaller , H. Punzmann , G. E. Schröder-Turk , M. Saadatfar

We investigate the structure and equilibrium linear-response dynamics of suspensions of hard colloidal dumbbells using Brownian Dynamics computer simulations. The focus lies on the dense fluid and plastic crystal states of the colloids with…

Soft Condensed Matter · Physics 2015-07-10 Nils Heptner , Joachim Dzubiella

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

An approach to obtain the structural properties of additive binary hard-sphere mixtures is presented. Such an approach, which is a nontrivial generalization of the one recently used for monocomponent hard-sphere fluids [S. Pieprzyk, A. C.…

Soft Condensed Matter · Physics 2020-01-20 S. Pieprzyk , A. C. Brańka , S. B. Yuste , A. Santos , M. López de Haro

Explicit simulations of fluid mixtures of highly size-dispersed particles are constrained by numerical challenges associated with identifying pair-interaction neighbors. Recent algorithmic developments have ameliorated these difficulties to…

Soft Condensed Matter · Physics 2022-12-07 Joseph M. Monti , Gary S. Grest

We explore phase behaviour of a binary colloidal system under external spatially periodic modulation. We perform Monte Carlo simulation on a binary mixture of big and small repulsive Lennard-Jones particles with diameter ratio 1:2. We…

Soft Condensed Matter · Physics 2023-07-31 Suravi Pal , Jaydeb Chakrabarti , Srabani Chakrabarty nee Sarkar

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks
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