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We estimate the prediction sensitivity with respect to Hartree-Fock exchange in approximate density functionals for representative Fe(II) and Fe(III) octahedral complexes. Based on the observation that the range of parameters spanned by the…

Materials Science · Physics 2015-07-16 Efthymios I. Ioannidis , Heather J. Kulik

A semi-relativistic density-functional theory that includes spin-orbit couplings and Zeeman fields on equal footing with the electromagnetic potentials, is an appealing framework to develop a unified first-principles computational approach…

Materials Science · Physics 2017-09-13 S. Pittalis , G. Vignale , F. G. Eich

Understanding the quantum dynamics of spin defects and their coherence properties requires accurate modeling of spin-spin interaction in solids and molecules, for example by using spin Hamiltonians with parameters obtained from…

Materials Science · Physics 2021-02-02 Krishnendu Ghosh , He Ma , Mykyta Onizhuk , Vikram Gavini , Giulia Galli

An efficient method to compute magnetic exchange interactions in systems with strong correlations is introduced. It is based on a magnetic force theorem which evaluates linear response due to rotations of magnetic moments and uses a novel…

Strongly Correlated Electrons · Physics 2007-05-23 Xiangang Wan , Quan Yin , Sergej Y. Savrasov

We present an ab initio investigation of magnetic exchange interactions using the spin-spiral method implemented in the VASP code, with a comparative analysis of the self-consistent (SC) and magnetic force theorem (MFT) approaches. Using…

Materials Science · Physics 2025-10-30 Umit Dogan Daglum , Maria Stamenova , Ersoy Sasioglu , Stefano Sanvito

The electronic and magnetic properties of neutral substitutional transition-metal dopants in dia- mond are calculated within density functional theory using the generalized gradient approximation to the exchange-correlation potential. Ti…

Materials Science · Physics 2015-06-03 Thomas Chanier , Craig Pryor , Michael E. Flatte'

Using generalizations of natural orbitals, spin-averaged natural orbitals, and two-particle charge correlators for solids, we investigate electronic structure of antiferromagnetic transition-metal oxides with a fully self-consistent,…

Strongly Correlated Electrons · Physics 2024-02-07 Pavel Pokhilko , Dominika Zgid

Theoretical calculations predict the dissipationless circulating current induced by a spin defect in a two-dimensional electron gas with spin-orbit coupling. The shape and spatial extent of these dissipationless circulating currents depend…

Mesoscale and Nanoscale Physics · Physics 2021-11-15 Adonai R. da Cruz , Michael E. Flatté

According to the Hohenberg-Kohn theorem of density-functional theory (DFT), all observable quantities of systems of interacting electrons can be expressed as functionals of the ground-state density. This includes, in principle, the spin…

Strongly Correlated Electrons · Physics 2019-09-04 Carsten A. Ullrich

Exact-exchange energy density and energy density of a semilocal density functional approximation are two key ingredients for modeling the static correlation, a strongly nonlocal functional of the density, through a local hybrid functional.…

Materials Science · Physics 2009-11-13 Jianmin Tao , Viktor N. Staroverov , Gustavo E. Scuseria , John P. Perdew

We investigate the dependence of the switching current density on the exchange stiffness constant in the spin transfer torque magnetic tunneling junction structure with micromagnetic simulations. Since the widely accepted analytic…

Materials Science · Physics 2015-06-05 Chun-Yeol You

We report on {\it ab initio} time-dependent spin dynamics simulations for a two-center magnetic molecular complex based on time-dependent non-collinear spin density functional theory. In particular, we discuss how the dynamical behavior of…

Other Condensed Matter · Physics 2015-06-16 Maria Stamenova , Stefano Sanvito

The accurate description of open-shell molecules, in particular of transition metal complexes and clusters, is still an important challenge for quantum chemistry. While density-functional theory (DFT) is widely applied in this area, the…

Chemical Physics · Physics 2012-10-26 Christoph R. Jacob , Markus Reiher

This article reviews steady-state spin densities and spin currents in materials with strong spin-orbit interactions. These phenomena are intimately related to spin precession due to spin-orbit coupling which has no equivalent in the steady…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Dimitrie Culcer

Spin-disorder resistivity of Fe and Ni and its temperature dependence are analyzed using noncollinear density functional calculations within the supercell method. Different models of thermal spin disorder are considered, including the…

Materials Science · Physics 2011-03-15 A. L. Wysocki , R. F. Sabirianov , M. van Schilfgaarde , K. D. Belashchenko

The evaluation of exact (Hartree--Fock, HF) exchange operator is a crucial ingredient for the accurate description of electronic structure in periodic systems through ab initio and hybrid density functional approaches. An efficient…

Chemical Physics · Physics 2020-10-28 Xiao Wang , Cannada A. Lewis , Edward F. Valeev

Spin fluctuations have a substantial influence on the electron and lattice behaviors in magnetic materials, which, however, is difficult to be tracked properly by prevalent first-principles methods. We propose a versatile self-adaptive…

Materials Science · Physics 2023-02-14 Zefeng Cai , Ke Wang , Yong Xu , Su-Huai Wei , Ben Xu

The prominence of density functional theory (DFT) in the field of electronic structure computation stems from its ability to usefully balance accuracy and computational effort. At the base of this ability is a functional of the electron…

We theoretically investigate quantum spin transfer from spin-correlated conduction-electron pairs to localized spins in a ferromagnet, given that electrons are correlated intrinsically. We show that even spin-singlet pairs and triplet pairs…

Mesoscale and Nanoscale Physics · Physics 2026-01-09 Seongmun Hwang , Jung Hyun Oh , Paul M. Haney , Mark D. Stiles , Kyung-Jin Lee

The swept-field experiments on magnetic molecular solids such as \Fe8 are studied using Monte Carlo simulations. A kinetic equation is developed to understand the phenomenon. It is found that the simulations provide a quantitatively…

Statistical Mechanics · Physics 2015-10-14 Erik Lenferink , Avinash Vijayaraghavan , Anupam Garg