Entanglement plays a central role in quantum technologies, yet its characterization and control in materials remain challenging. Recent developments in spectrum-based entanglement witnesses have enabled new strategies for quantifying many-body entanglement in macroscopic materials. Here, we develop a protocol for detecting spin--orbital entanglement using experiment-accessible resonant inelastic x-ray scattering (RIXS). Central to our approach is the construction of a Hermitian generator from experimentally measurable spectra, which allows us to compute the quantum Fisher information (QFI) available in spin--orbital systems. The resulting QFI provides upper bounds for k-producible states and thus serves as a robust witness of spin--orbital entanglement. To account for realistic experimental limitations, we further extend our framework to include relaxed QFI bounds applicable to measurements lacking full polarization resolution.
@article{arxiv.2512.06718,
title = {Witnessing Spin-Orbital Entanglement using Resonant Inelastic X-Ray Scattering},
author = {Zecheng Shen and Shuhan Ding and Zijun Zhao and Francesco A. Evangelista and Yao Wang},
journal= {arXiv preprint arXiv:2512.06718},
year = {2025}
}