Why is the ground state electron configuration for Lithium $1s^22s$ ?
Atomic Physics
2015-11-17 v1 Strongly Correlated Electrons
Abstract
The electronic ground state for Lithium is , and not . The traditional argument for why this is so is based on a screening argument that claims that the electron is better shielded by the electrons, and therefore higher in energy then the configuration that includes the electron. We show that this argument is flawed, and in fact the actual reason for the ordering is because the electron-electron interaction energy is higher for the repulsion than it is for the repulsion.
Cite
@article{arxiv.1211.3240,
title = {Why is the ground state electron configuration for Lithium $1s^22s$ ?},
author = {W. S. Stacey and F. Marsiglio},
journal= {arXiv preprint arXiv:1211.3240},
year = {2015}
}
Comments
4 pages