English

What makes a complex liquid complex?

Disordered Systems and Neural Networks 2012-05-11 v3 Soft Condensed Matter Statistical Mechanics

Abstract

We view a complex liquid as a network of bonds connecting each particle to its nearest neighbors; the dynamics of this network is a chain of discrete events signaling particles rearrangements. Within this picture, we studied a two-dimensional complex liquid and found a stretched-exponential decay of the network memory and a power-law for the distribution of the times for which a particle keeps its nearest neighbors; the dependence of this distribution on temperature suggests a possible dynamical critical point. We identified and quantified the underlying spatio-temporal phenomena. The equilibrium liquid represents a hierarchical structure, a mosaic of long-living crystallites partially separated by less-ordered regions. The long-time dynamics of this structure is dominated by particles redistribution between dynamically and structurally different regions. We argue that these are generic features of locally ordered but globally disordered complex systems. In particular, these features must be taken into account by any coarse-grained theory of dynamics of complex fluids and glasses.

Keywords

Cite

@article{arxiv.1201.4498,
  title  = {What makes a complex liquid complex?},
  author = {Alexander Z. Patashinski and Rafal Orlik and Antoni C. Mitus and Mark A. Ratner and Bartosz A. Grzybowski},
  journal= {arXiv preprint arXiv:1201.4498},
  year   = {2012}
}

Comments

16 pages, 4 Figures

R2 v1 2026-06-21T20:07:58.536Z