English

Visible line intensities of the triatomic hydrogen ion from experiment and theory

Chemical Physics 2015-04-13 v1

Abstract

The visible spectrum of H3+ is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of H3+ up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein BB coefficients. {\it Ab initio} predictions for the Einstein BB coefficients are obtained from a highly precise dipole moment surface of H3+ and found to be in excellent agreement, even in the region where states have been classified as chaotic.

Keywords

Cite

@article{arxiv.1501.00896,
  title  = {Visible line intensities of the triatomic hydrogen ion from experiment and theory},
  author = {Annemieke Petrignani and Max H. Berg and Florian Grussie and Andreas Wolf and Irina I. Mizus and Oleg L. Polyansky and Jonathan Tennyson and Nikolai F. Zobov and Michele Pavanello and Ludwik Adamowicz},
  journal= {arXiv preprint arXiv:1501.00896},
  year   = {2015}
}

Comments

4 pages, 1 figure