Vibrationally induced flip motion of a hydroxyl dimer on Cu(110)
Abstract
Recent low-temperature scanning-tunneling microscopy experiments [T. Kumagai et al., Phys. Rev. B 79, 035423 (2009)] observed the vibrationally induced flip motion of a hydroxyl dimer (OD)2 on Cu(110). We propose a model to describe two-level fluctuations and current-voltage characteristics of nanoscale systems which undergo vibrationally induced switching. The parameters of the model are based on comprehensive density-functional calculations of the system's vibrational properties. For the dimer (OD)2 the calculated population of the high and low conductance states, the I-V, dI/dV, and d2I/dV2 curves are in good agreement with the experimental results and underlines the different roles played by the free and shared OD stretch modes of the dimer.
Keywords
Cite
@article{arxiv.1111.2252,
title = {Vibrationally induced flip motion of a hydroxyl dimer on Cu(110)},
author = {Yasuhiro Ootsuka and Thomas Frederiksen and Hiromu Ueba and Magnus Paulsson},
journal= {arXiv preprint arXiv:1111.2252},
year = {2011}
}
Comments
5 pages, 4 figures