English

Vibrational Study of 13C-enriched C60 Crystals

Condensed Matter 2009-10-22 v1

Abstract

The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes. Symmetry breaking due to 13C isotopes provides a possible route for optically activating IR-silent vibrational modes. Experimental spectra and a semi-empirical theory on natural abundance and 13C-enriched single crystals of C60 are presented. By comparing the experimental results with the theoretical results, we exclude this isotopic activation mechanism from the explanation for weakly active fundamentals in the spectra.

Cite

@article{arxiv.cond-mat/9411032,
  title  = {Vibrational Study of 13C-enriched C60 Crystals},
  author = {Michael C. Martin and J. Fabian and J. Godard and P. Bernier and J. M. Lambert and L. Mihaly},
  journal= {arXiv preprint arXiv:cond-mat/9411032},
  year   = {2009}
}

Comments

Accepted for Phys. Rev. B, typeset in REVTEX v3.0 in LaTeX. Postscript file including figures is available at http://insti.physics.sunysb.edu/~mmartin/papers/c13twocol2.ps File with figures will be e-mailed by request

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