Thermionic emission from monolayer graphene grown on representative transition metals, Ir and Ru, is characterized by low-energy electron microscopy (LEEM). Work functions were determined from the temperature dependence of the emission current and from the electron energy spectrum of emitted electrons. The high-temperature work function of the strongly interacting system graphene/Ru(0001) is sufficiently low, 3.3 \pm 0.1 eV, to have technological potential for large-area emitters that are spatially uniform, efficient, and chemically inert. The thermionic work functions of the less strongly interacting system graphene/Ir(111) are over 1 eV larger and vary substantially (0.4 eV) between graphene orientations rotated by 30{\deg}.
@article{arxiv.1204.5260,
title = {Viable thermionic emission from graphene-covered metals},
author = {Elena Starodub and Norman C. Bartelt and Kevin F. McCarty},
journal= {arXiv preprint arXiv:1204.5260},
year = {2012}
}