English

Vanishing RKKY interactions in Ce-based cage compounds

Strongly Correlated Electrons 2023-09-08 v1 Materials Science

Abstract

We report the results of thermodynamic measurements in external magnetic field of the cubic Ce-based cage compounds CeT2T_{2}Cd20_{20} (TT = Ni,Pd). Our analysis of the heat-capacity data shows that the Γ7\Gamma_7 doublet is the ground state multiplet of the Ce3+^{3+} ions. Consequently, for the Γ7\Gamma_7 doublet it can be theoretically shown that the Ruderman-Kittel-Kasuya-Yosida (RKKY) interaction between the localized Ce moments mediated by the conduction electrons, must vanish at temperatures much lower than the energy separating the ground state doublet from the first excited Γ8\Gamma_8 quartet. Our findings provide an insight as to why no long range order has been observed in these compounds down to temperatures in the millikelvin range.

Cite

@article{arxiv.2212.07586,
  title  = {Vanishing RKKY interactions in Ce-based cage compounds},
  author = {A. M. Konic and Y. Zhu and A. J. Breindel and Y. Deng and C. M. Moir and M. B. Maple and C. C. Almasan and M. Dzero},
  journal= {arXiv preprint arXiv:2212.07586},
  year   = {2023}
}

Comments

5 pages, 4 figures

R2 v1 2026-06-28T07:35:42.622Z