Increasing the efficiency of charge transfer and separation efficiency of photogenerated carriers are still the main challenges in the field of semiconductor-based photocatalysts. Herein, we synthesized g-C3N4@V2C MXene photocatalyst by modifying g-C3N4 using V2C MXene. The prepared photocatalyst exhibited outstanding photocatalytic performance under visible light. The degradation efficiency of methyl orange by g-C3N4@V2C MXene photocatalyst was as high as 94.5%, which is 1.56 times higher than that by g-C3N4. This was attributed to the V2C MXene inhibiting the rapid recombination of photogenerated carriers and facilitating rapid transfer of photogenerated electrons (e) from g-C3N4 to MXene. Moreover, g-C3N4@V2C MXene photocatalyst showed good cycling stability. The photocatalytic performance was higher than 85% after three cycles. Experiments to capture free radicals revealed that superoxide radicals (02) are the main contributors to the photocatalytic activity. Thus, the proposed g-C3N4@V2C MXene photocatalyst is a promising visible-light catalyst.
@article{arxiv.2310.16414,
title = {V2C MXene-modified g-C3N4 for enhanced visible-light photocatalytic activity},
author = {Ruizheng Xu and Guiyu Wei and Zhemin Xie and Sijie Diao and Jianfeng Wen and Tao Tang and Li Jiang and Ming Li and Guanghui Hu},
journal= {arXiv preprint arXiv:2310.16414},
year = {2023}
}