Uncorrelated Volatile Behavior During the 2011 Apparition of Comet C/2009 P1 Garradd

The High Resolution Instrument Infrared Spectrometer (HRI-IR) onboard the Deep Impact Flyby spacecraft detected H2O, CO2, and CO in the coma of the dynamically young Oort cloud comet C/2009 P1 (Garradd) post-perihelion at a heliocentric distance of 2 AU. Production rates were derived for the parent volatiles, QH2O = 4.6e28, QCO2 = 3.9e27, and QCO = 2.9e28 molecules s-1, and are consistent with the trends seen by other observers and within the error bars of measurements acquired during a similar time period. When compiled with other observations of the dominant volatiles of Garradd, unexpected behavior was seen in the release of CO. The H2O outgassing of Garradd, increasing and peaking pre-perihelion and then steadily decreasing, is more typical than that of CO, which monotonically increased throughout the entire apparition. Due to the temporal asymmetry in volatile release, Garradd exhibited the highest CO to H2O abundance ratio ever observed for any comet inside the water snow line at 60 percent during the HRI-IR observations. Also, the HRI-IR made the only direct measurement of CO2, giving a typical cometary abundance ratio of CO2 to H2O of 8 percent but, with only one measurement, no sense of how it varied with orbital position.