VI3 is a ferromagnet with planar honeycomb sheets of bonded V3+ ions held together by van der Waals forces. We apply neutron spectroscopy to measure the two dimensional (J/Jc≈17) magnetic excitations in the ferromagnetic phase, finding two energetically gapped (Δ≈kBTc≈ 55 K) and dispersive excitations. We apply a multi-level spin wave formalism to describe the spectra in terms of two coexisting domains hosting differing V3+ orbital ground states built from contrasting distorted octahedral environments. This analysis fits a common nearest neighbor in-plane exchange coupling (J=-8.6 ± 0.3 meV) between V3+ sites. The distorted local crystalline electric field combined with spin-orbit coupling provides the needed magnetic anisotropy for spatially long-ranged two-dimensional ferromagnetism in VI3.
@article{arxiv.2107.04311,
title = {Two-dimensional ferromagnetic spin-orbital excitations in the honeycomb VI$_{3}$},
author = {H. Lane and E. Pachoud and J. A. Rodriguez-Rivera and M. Songvilay and G. Xu and P. M. Gehring and J. P. Attfield and R. A. Ewings and C. Stock},
journal= {arXiv preprint arXiv:2107.04311},
year = {2021}
}
Comments
(main text - 7 pages, 4 figures; supplementary information - 13 pages, 9 figures, to be published in Phys. Rev. B)