Two-dimensional bismuth (Bi) is a promising platform for quantum and energy technologies due to strong spin-orbit coupling, high thermoelectric efficiency, and magnetoresistance. However, scalable and flexible synthesis of high-quality Bi with fast research turnaround remains challenging. We report a controlled colloidal synthesis of Bi nanosheets with tunable lateral sizes (0.6 - 4.1 um), hexagonal shape, and a layered single-crystalline structure along the {00l} planes. The nanosheets exhibit excellent oxidation resistance and ambient stability. ARPES measurements on individual nanosheets reveal a band structure in excellent agreement with DFT calculations, confirming high crystal quality and uniformity. Our findings enable fast production and characterization of two-dimensional Bi, paving the way for fundamental studies and integration into next-generation quantum and energy devices.
@article{arxiv.2510.26558,
title = {Tunable Colloidal Synthesis Enabling {\mu}-ARPES on Individual Two-dimensional Bismuth Nanocrystals},
author = {Fagui He and Yan Yan Grisan Qiu and Simone Mearini and Vitaliy Feyer and Kevin Oldenburg and Rostyslav Lesyuk and Christian Klinke},
journal= {arXiv preprint arXiv:2510.26558},
year = {2025}
}