English

Trial wave functions for High-Pressure Metallic Hydrogen

Computational Physics 2009-11-13 v1

Abstract

Many body trial wave functions are the key ingredient for accurate Quantum Monte Carlo estimates of total electronic energies in many electron systems. In the Coupled Electron-Ion Monte Carlo method, the accuracy of the trial function must be conjugated with the efficiency of its evaluation. We report recent progress in trial wave functions for metallic hydrogen implemented in the Coupled Electron-Ion Monte Carlo method. We describe and characterize several types of trial functions of increasing complexity in the range of the coupling parameter 1.0rs1.551.0 \leq r_s \leq1.55. We report wave function comparisons for disordered protonic configurations and preliminary results for thermal averages.

Keywords

Cite

@article{arxiv.0712.0161,
  title  = {Trial wave functions for High-Pressure Metallic Hydrogen},
  author = {Carlo Pierleoni and Kris T. Delaney and Miguel A. Morales and David M. Ceperley and Markus Holzmann},
  journal= {arXiv preprint arXiv:0712.0161},
  year   = {2009}
}

Comments

11 pages, 6 figures, submitted to Computer Physics Communications

R2 v1 2026-06-21T09:49:33.491Z