English

Threshold surface reactions and local time resetting

Statistical Mechanics 2022-04-12 v2

Abstract

In this paper we consider a threshold surface absorption mechanism for a particle diffusing in a domain containing a single target \calU\calU . The target boundary \calU\partial \calU is taken to be a reactive surface that modifies an internal state ZtZ_t of the particle when in contact with the surface at time tt, with Z0=hZ_0=h. The state ZtZ_t is taken to be a monotonically decreasing function of the so-called boundary local time, and absorption occurs as soon as ZtZ_t reaches zero. (The boundary local time is a Brownian functional that determines the amount of time that the particle spends in a neighborhood of \calU\partial \calU.) We first show how to analyze threshold surface absorption in terms of the joint probability density or generalized propagator P0(\x,,t\x0)P_0(\x,\ell,t|\x_0) for the pair (\Xt,t)(\X_t,\ell_t) in the case of a perfectly reflecting surface, where \Xt\X_t and t\ell_t denote the particle position and local time at time tt, respectively, and \x0\x_0 is the initial position. We then introduce a generalized stochastic resetting protocol in which both the position \Xt\X_t and the internal state ZtZ_t are reset to their initial values, \Xt\x0\X_t\rightarrow \x_0 and ZthZ_t\rightarrow h, at a Poisson rate rr. The latter is mathematically equivalent to resetting the boundary local time, t0\ell_t\rightarrow 0. Since resetting is governed by a renewal process, the survival probability with resetting can be expressed in terms of the survival probability without resetting, which means that the statistics of absorption can be determined by calculating the Laplace transform of P0(\x,,t\x0)P_0(\x,\ell,t|\x_0) with respect to tt. We contrast this with the case where only particle position is reset, which is not governed by a renewal process. We illustrate the theory using the simple examples of diffusion on the half-line and a spherical target in a spherical domain.

Keywords

Cite

@article{arxiv.2203.04868,
  title  = {Threshold surface reactions and local time resetting},
  author = {Paul C. Bressloff},
  journal= {arXiv preprint arXiv:2203.04868},
  year   = {2022}
}

Comments

23 pages, 8 figures

R2 v1 2026-06-24T10:07:37.133Z