English

Three-point susceptibilities $\chi_n(k;t)$ and $\chi_n^s(k;t)$: mode-coupling approximation

Soft Condensed Matter 2009-11-13 v1 Statistical Mechanics

Abstract

Recently, it was argued that a three-point susceptibility equal to the density derivative of the intermediate scattering function, χn(k;t)=dF(k;t)/dn\chi_n(k;t) = d F(k;t)/d n, enters into an expression for the divergent part of an integrated four-point dynamic density correlation function of a colloidal suspension [Berthier \textit{et al.}, J. Chem. Phys. \textbf{126}, 184503 (2007)]. We show that, within the mode-coupling theory, the equation of motion for χn(k;t)\chi_n(k;t) is essentially identical as the equation of motion for the q0\mathbf{q}\to 0 limit of the three-point susceptibility χq(k;t)\chi_{\mathbf{q}}(\mathbf{k};t) introduced by Biroli \textit{et al.} [Phys. Rev. Lett. \textbf{97}, 195701 (2006)]. We present a numerical solution of the equation of motion for χn(k;t)\chi_n(k;t). We also derive and numerically solve an equation of motion for the density derivative of the self-intermediate scattering function, χns(k;t)=dFs(k;t)/dn\chi_n^s(k;t) = d F^s(k;t)/d n. We contrast the wave vector dependence of χn(k;t)\chi_n(k;t) and χns(k;t)\chi_n^s(k;t).

Keywords

Cite

@article{arxiv.0810.3636,
  title  = {Three-point susceptibilities $\chi_n(k;t)$ and $\chi_n^s(k;t)$: mode-coupling approximation},
  author = {Grzegorz Szamel and Elijah Flenner},
  journal= {arXiv preprint arXiv:0810.3636},
  year   = {2009}
}