English

Thoroughly analysis of the phase diagram for the Bell-Lavis model: An entropic simulational study

Statistical Mechanics 2021-04-14 v1

Abstract

In this work, we investigate the Bell-Lavis model using entropic simulations for several values of the energy parameters. The T×μT\times\mu phase diagram and the ground state configurations are analyzed thoroughly. Besides, we examine the particle density and specific heat behavior for different values of the chemical potential μ\mu as functions of temperature. We also obtain configurations that maximize the canonical probability for several values of chemical potential and temperature, enabling the identification of the low density (LDLLDL) and high-density liquid (HDLHDL) phases, among others, in the critical regions. We found a second-order phase transition from the LDLHDL0LDL-HDL_0 to LDLHDLLDL-HDL coexistence in the range of 0<μ<1.055030<\mu<1.05503. In the 1.05503<μ<1.480241.05503<\mu<1.48024 range, the transition between the LDLHDL0LDL-HDL_0 and LDLHDL0emptyLDL-HDL_0-empty coexistence presents discontinuous and continuous transitions characteristics. Finally, for 1.48024<μ<1.51.48024<\mu<1.5, the phase transition between LDLLDL and emptyempty phases is of first-order.

Keywords

Cite

@article{arxiv.2008.01028,
  title  = {Thoroughly analysis of the phase diagram for the Bell-Lavis model: An entropic simulational study},
  author = {L. S. Ferreira and L. N. Jorge and Cláudio J. DaSilva and A. A. Caparica},
  journal= {arXiv preprint arXiv:2008.01028},
  year   = {2021}
}

Comments

10 pages, 12 figures