Thermodynamics of glasses: a first principle computation
Condensed Matter
2016-08-31 v1
Abstract
We propose a first principle computation of the thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.
Keywords
Cite
@article{arxiv.cond-mat/9807420,
title = {Thermodynamics of glasses: a first principle computation},
author = {Marc Mezard and Giorgio Parisi},
journal= {arXiv preprint arXiv:cond-mat/9807420},
year = {2016}
}
Comments
Latex, 13 pages, 4 figures