English

Thermodynamics of glasses: a first principle computation

Condensed Matter 2016-08-31 v1

Abstract

We propose a first principle computation of the thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting molecules, each molecule being built of mm atoms, and having a gyration radius (related to the cage size) which vanishes at zero temperature. We use a small cage expansion, valid at low temperatures, which allows to compute the cage size, the specific heat (which follows the Dulong and Petit law), and the configurational entropy.

Keywords

Cite

@article{arxiv.cond-mat/9807420,
  title  = {Thermodynamics of glasses: a first principle computation},
  author = {Marc Mezard and Giorgio Parisi},
  journal= {arXiv preprint arXiv:cond-mat/9807420},
  year   = {2016}
}

Comments

Latex, 13 pages, 4 figures