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Thermodynamics of a hierarchical mixture of cubes

Mathematical Physics 2020-03-26 v2 math.MP Probability

Abstract

We investigate a toy model for phase transitions in mixtures of incompressible droplets. The model consists of non-overlapping hypercubes in Zd\mathbb Z^d of sidelengths 2j2^j, jN0j\in N_0. Cubes belong to an admissible set B\mathbb B such that if two cubes overlap, then one is contained in the other. Cubes of sidelength 2j2^j have activity zjz_j and density ρj\rho_j. We prove explicit formulas for the pressure and entropy, prove a van-der-Waals type equation of state, and invert the density-activity relations. In addition we explore phase transitions for parameter-dependent activities zj(μ)=exp(2djμEj)z_j(\mu) = \exp( 2^{dj} \mu - E_j). We prove a sufficient criterion for absence of phase transition, show that constant energies EjλE_j\equiv\lambda lead to a continuous phase transition, and prove a necessary and sufficient condition for the existence of a first-order phase transition.

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Cite

@article{arxiv.1909.09546,
  title  = {Thermodynamics of a hierarchical mixture of cubes},
  author = {Sabine Jansen},
  journal= {arXiv preprint arXiv:1909.09546},
  year   = {2020}
}

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31 pages