Thermodynamics of a hierarchical mixture of cubes
Abstract
We investigate a toy model for phase transitions in mixtures of incompressible droplets. The model consists of non-overlapping hypercubes in of sidelengths , . Cubes belong to an admissible set such that if two cubes overlap, then one is contained in the other. Cubes of sidelength have activity and density . We prove explicit formulas for the pressure and entropy, prove a van-der-Waals type equation of state, and invert the density-activity relations. In addition we explore phase transitions for parameter-dependent activities . We prove a sufficient criterion for absence of phase transition, show that constant energies lead to a continuous phase transition, and prove a necessary and sufficient condition for the existence of a first-order phase transition.
Keywords
Cite
@article{arxiv.1909.09546,
title = {Thermodynamics of a hierarchical mixture of cubes},
author = {Sabine Jansen},
journal= {arXiv preprint arXiv:1909.09546},
year = {2020}
}
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31 pages