English

Thermal mean-field theories

Statistical Mechanics 2024-08-21 v3 Chemical Physics

Abstract

Several closely related ab initio thermal mean-field theories for fermions, both well-established and new ones, are compared with one another at the formalism level and numerically. The theories considered are Fermi-Dirac theory, thermal Hartree-Fock (HF) theory, two modifications of the thermal single-determinant approximation of Kaplan and Argyres, and first-order finite-temperature many-body perturbation theory based on zero-temperature or thermal HF reference. The thermal full-configuration-interaction theory is used as the benchmark.

Keywords

Cite

@article{arxiv.2407.11508,
  title  = {Thermal mean-field theories},
  author = {Pinhao Gu and So Hirata},
  journal= {arXiv preprint arXiv:2407.11508},
  year   = {2024}
}
R2 v1 2026-06-28T17:42:43.191Z