English

The two colors of MgB2

Superconductivity 2013-01-24 v2

Abstract

We present the anisotropic optical conductivity of MgB2_{2} between 0.1 and 3.7 eV at room temperature obtained on single crystals of different purity by the spectroscopic ellipsometry and reflectance measurements. The bare (unscreened) plasma frequency ωp\omega_{p} is almost isotropic and equal to 6.3 eV, which contrasts some earlier reports of a very small value of ωp\omega_{p}. The data suggests that the σ\sigma-bands are characterized by a stronger electron-phonon coupling λtr\lambda_ {tr} but smaller impurity scattering γimp\gamma_{imp}, compared to the π\pi-bands. The optical response along the boron planes is marked by an intense interband transition at 2.6 eV, due to which the reflectivity plasma edges along the a- and c-axes are shifted with respect to each other. As a result, the sample spectacularly changes color from a blueish-silver to the yellow as the polarization is rotated from the in-plane direction towards the c-axis. The optical spectra are in good agreement with the published {\it ab initio} calculations. The remaining discrepancies can be explained by the relative shift of σ\sigma-bands and π\pi-bands by about 0.2 eV compared to the theoretical band structure, in agreement with the de Haas-van Alphen experiments. The widths of the Drude and the interband peaks are both very sensitive to the sample purity.

Keywords

Cite

@article{arxiv.cond-mat/0509345,
  title  = {The two colors of MgB2},
  author = {V. Guritanu and A. B. Kuzmenko and D. van der Marel and S. M. Kazakov and N. D. Zhigadlo and J. Karpinski},
  journal= {arXiv preprint arXiv:cond-mat/0509345},
  year   = {2013}
}

Comments

11 pages, 13 figures