The Spin Zone: Synchronously and Asynchronously Rotating Exoplanets Have Spectral Differences in Transmission

New observational facilities are beginning to enable insights into the three-dimensional (3D) nature of exoplanets. Transmission spectroscopy is the most widely used method for characterizing transiting temperate exoplanet's atmospheres, but because it only provides a glimpse of the planet's limb and nightside for a typical orbit, its ability to probe 3D characteristics is still an active area of research. Here, we use the ROCKE-3D general circulation model to test the impact of synchronization state, a ``low-order'' 3D characteristic previously shown to drive differences in planetary phase curves, on the transmission spectrum of a representative super-Earth land planet across temperate-to-warm instellations (S$_p$=0.8, 1, 1.25, 1.66, 2, 2.5, 3, 4, 4.56~S$_\oplus$). We find that different synchronization states do display differences in their transmission spectra, primarily driven by clouds and humidity, and that the differences shrink or disappear in hotter regimes where water clouds are unable to condense (though our simulations do not consider haze formation). The small size of the feature differences and potential for degeneracy with other properties, like differing water content or atmospheric structure, mean that we do not specifically claim to have identified a single transmission diagnostic for synchronization state, but our results can be used for holistic spectrum interpretation and sample creation, and suggest the need for more modelling in this area.