The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure
Abstract
The theoretical maximum critical temperature () for conventional superconductors at ambient pressure remains a fundamental question in condensed matter physics. Through analysis of electron-phonon calculations for over 20,000 metals, we critically examine this question. We find that while hydride metals can exhibit maximum phonon frequencies of more than 5000 K, the crucial logarithmic average frequency rarely exceeds 1800 K. Our data reveals an inherent trade-off between and the electron-phonon coupling constant , suggesting that the optimal Eliashberg function that maximizes is unphysical. Based on our calculations, we identify LiAgH and its sibling LiAuH as theoretical materials that likely approach the practical limit for conventional superconductivity at ambient pressure. Analysis of thermodynamic stability indicates that compounds with higher predicted values are increasingly unstable, making their synthesis challenging. While fundamental physical laws do not strictly limit to low-temperatures, our analysis suggests that achieving room-temperature conventional superconductivity at ambient pressure is extremely unlikely.
Keywords
Cite
@article{arxiv.2502.18281,
title = {The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure},
author = {Kun Gao and Tiago F. T. Cerqueira and Antonio Sanna and Yue-Wen Fang and Đorđe Dangić and Ion Errea and Hai-Chen Wang and Silvana Botti and Miguel A. L. Marques},
journal= {arXiv preprint arXiv:2502.18281},
year = {2025}
}