English

The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure

Superconductivity 2025-10-24 v1

Abstract

The theoretical maximum critical temperature (TcT_c) for conventional superconductors at ambient pressure remains a fundamental question in condensed matter physics. Through analysis of electron-phonon calculations for over 20,000 metals, we critically examine this question. We find that while hydride metals can exhibit maximum phonon frequencies of more than 5000 K, the crucial logarithmic average frequency ωlog\omega_\text{log} rarely exceeds 1800 K. Our data reveals an inherent trade-off between ωlog\omega_\text{log} and the electron-phonon coupling constant λ\lambda, suggesting that the optimal Eliashberg function that maximizes TcT_c is unphysical. Based on our calculations, we identify Li2_2AgH6_6 and its sibling Li2_2AuH6_6 as theoretical materials that likely approach the practical limit for conventional superconductivity at ambient pressure. Analysis of thermodynamic stability indicates that compounds with higher predicted TcT_c values are increasingly unstable, making their synthesis challenging. While fundamental physical laws do not strictly limit TcT_c to low-temperatures, our analysis suggests that achieving room-temperature conventional superconductivity at ambient pressure is extremely unlikely.

Keywords

Cite

@article{arxiv.2502.18281,
  title  = {The Maximum $T_c$ of Conventional Superconductors at Ambient Pressure},
  author = {Kun Gao and Tiago F. T. Cerqueira and Antonio Sanna and Yue-Wen Fang and Đorđe Dangić and Ion Errea and Hai-Chen Wang and Silvana Botti and Miguel A. L. Marques},
  journal= {arXiv preprint arXiv:2502.18281},
  year   = {2025}
}