English

The glass susceptibility: growth kinetics and saturation under shear

Soft Condensed Matter 2016-07-08 v1 Statistical Mechanics

Abstract

We study the growth kinetics of glassy correlations in a structural glass by monitoring the evolution, within mode-coupling theory, of a suitably defined three-point function χC(t,tw)\chi_C(t,t_w) with time tt and waiting time twt_w. From the complete wave vector-dependent equations of motion for domain growth we pass to a schematic limit to obtain a numerically tractable form. We find that the peak value χCP\chi_C^P of χC(t,tw)\chi_C(t,t_w), which can be viewed as a correlation volume, grows as tw0.5t_w^{0.5}, and the relaxation time as tw0.8t_w^{0.8}, following a quench to a point deep in the glassy state. These results constitute a theoretical explanation of the simulation findings of Parisi [J. Phys. Chem. B {\bf 103}, 4128 (1999)] and Kob and Barrat [Phys. Rev. Lett. {\bf 78}, 4581 (1997)] and are also in qualitative agreement with Parsaeian and Castillo [Phys. Rev. E {\bf 78}, 060105(R) (2008)]. On the other hand, if the quench is to a point on the {\em liquid side}, the correlation volume grows to saturation. We present a similar calculation for the growth kinetics in a pp-spin spin glass mean-field model where we find a slower growth, χCPtw0.13\chi_C^P \sim t_w^{0.13}. Further, we show that a shear rate \gdot\gdot cuts off the growth of glassy correlations when tw1/\gdott_w\sim 1/\gdot for quench in the glassy regime and tw=min(tr,1/\gdot)t_w=\min(t_r,1/\gdot) in the liquid, where trt_r is the relaxation time of the unsheared liquid. The relaxation time of the steady state fluid in this case is \gdot0.8\propto \gdot^{-0.8}.

Keywords

Cite

@article{arxiv.1309.2389,
  title  = {The glass susceptibility: growth kinetics and saturation under shear},
  author = {Saroj Kumar Nandi and Sriram Ramaswamy},
  journal= {arXiv preprint arXiv:1309.2389},
  year   = {2016}
}

Comments

This is the extended version, with several new results, of our paper Phys. Rev. Lett. 109, 115702 (2012), archived as arXiv:1205.1152