The Dustiest Galactic S Stars: Mid-Infrared Spectra from SOFIA/FORCAST

We present spectra of 12 of the reddest, and hence dustiest, S stars in the Milky Way, observed with the FORCAST grisms on SOFIA. S stars are asymptotic giant branch (AGB) stars with C/O$\sim$1, so their molecular and dust chemistries are dominated by neither O nor C, often leading to atypical spectral features from their molecules and dust grains. All of the stars in our sample have strong dust emission features at 10--11 $\mu$m, but the shape of the feature in most of the stars differs from the shapes commonly observed in either oxygen-rich or carbon-rich AGB stars. Two stars also show the 13 $\mu$m feature associated with crystalline alumina. Two have a water absorption band at $\sim$6.5--7.5 $\mu$m, and a third has a tentative detection, but only one of these three has the more common SiO absorption band at 7.5 $\mu$m. Three others show a red 6.3 $\mu$m emission feature from complex hydrocarbons consistent with ``Class C'' objects, and in a fourth it appears at 6.37 $\mu$m, redder than even the standard Class C hydrocarbon feature. Class C spectra typically indicate complex hydrocarbons which have been less processed by UV radiation, resulting in more aliphatic bonds relative to aromatic bonds. None of the S stars shows a strong 11.3 $\mu$m hydrocarbon feature, which is also consistent with the presence of aliphatic hydrocarbons.