Symmetry for the duration of entropy-consuming intervals
Abstract
We introduce the violation fraction as the cumulative fraction of time that a mesoscopic system spends consuming entropy at a single trajectory in phase space. We show that the fluctuations of this quantity are described in terms of a symmetry relation reminiscent of fluctuation theorems, which involve a function, , which can be interpreted as an entropy associated to the fluctuations of the violation fraction. The function , when evaluated for arbitrary stochastic realizations of the violation fraction, is odd upon the symmetry transformations which are relevant for the associated stochastic entropy production. This fact leads to a detailed fluctuation theorem for the probability density function of . We study the steady-state limit of this symmetry in the paradigmatic case of a colloidal particle dragged by optical tweezers through an aqueous solution. Finally, we briefly discuss on possible applications of our results for the estimation of free-energy differences from single molecule experiments.
Keywords
Cite
@article{arxiv.1403.2421,
title = {Symmetry for the duration of entropy-consuming intervals},
author = {Reinaldo García-García and Daniel Domínguez},
journal= {arXiv preprint arXiv:1403.2421},
year = {2014}
}
Comments
11 pages, 4 figures. Last revised. Version accepted for publication in Phys. Rev. E