English

Symmetry for the duration of entropy-consuming intervals

Statistical Mechanics 2014-05-19 v2

Abstract

We introduce the violation fraction υ\upsilon as the cumulative fraction of time that a mesoscopic system spends consuming entropy at a single trajectory in phase space. We show that the fluctuations of this quantity are described in terms of a symmetry relation reminiscent of fluctuation theorems, which involve a function, Φ\Phi, which can be interpreted as an entropy associated to the fluctuations of the violation fraction. The function Φ\Phi, when evaluated for arbitrary stochastic realizations of the violation fraction, is odd upon the symmetry transformations which are relevant for the associated stochastic entropy production. This fact leads to a detailed fluctuation theorem for the probability density function of Φ\Phi. We study the steady-state limit of this symmetry in the paradigmatic case of a colloidal particle dragged by optical tweezers through an aqueous solution. Finally, we briefly discuss on possible applications of our results for the estimation of free-energy differences from single molecule experiments.

Keywords

Cite

@article{arxiv.1403.2421,
  title  = {Symmetry for the duration of entropy-consuming intervals},
  author = {Reinaldo García-García and Daniel Domínguez},
  journal= {arXiv preprint arXiv:1403.2421},
  year   = {2014}
}

Comments

11 pages, 4 figures. Last revised. Version accepted for publication in Phys. Rev. E