English

Superconductivity of $LaH_{10}$ and $LaH_{16}$ polyhydrides

Superconductivity 2020-02-04 v5

Abstract

We explore high-pressure phase stability and superconductivity of lanthanum hydrides LaHmLaH_m (m=4-11,16). We predict stability of a hitherto unreported polyhydride P6/mmmP6/mmm-LaH16LaH_{16} at pressures above 150 GPa; at 200 GPa its predicted superconducting TCT_C is 156 K, critical field μ0\mu_0HCH_C(0) ~ 35 T and superconducting gap is up to 35 meV. We revisit superconductivity of the recently discovered LaH10LaH_{10} and find its TCT_C to be up to 259 K (170 GPa) from solving the Eliashberg equation and 271 K from solving the gap equation in SCDFT which also allowed us to compute the Coulomb pseudopotential μ\mu^* for LaH10LaH_{10} and LaH16LaH_{16}. Presence of several polymorph modifications of LaH10 may explain the variety in the experimentally measured TCT_C values for LaH10LaH_{10} [1,2]

Keywords

Cite

@article{arxiv.1810.01113,
  title  = {Superconductivity of $LaH_{10}$ and $LaH_{16}$ polyhydrides},
  author = {Ivan A. Kruglov and Dmitrii V. Semenok and Hao Song and Radosław Szczęśniak and Izabela A. Wrona and Ryosuke Akashi and M. Mahdi Davari Esfahani and Defang Duan and Tian Cui and Alexander G. Kvashnin and Artem R. Oganov},
  journal= {arXiv preprint arXiv:1810.01113},
  year   = {2020}
}

Comments

11 pages including 4 figures, 2 tables, Supporting Information (23 pages)