Motivated by the exploration of bipolaronic superconductivity in conducting polymers, we examine such a possibility in the starting member of p-oligophenyls −p-terphenyl with three phenyl rings, belonging to the family of conducting polymer polyparaphenylene. The formation of bipolarons is identified from Raman scattering measurements. Both the dc and ac magnetic susceptibility measurements reveal that p-terphenyl is a type-II superconductor with a critical temperature of 7.2 K upon doping potassium. The electron-lattice interaction, manifested by pronounced bipolaronic bands, is suggested to account for the observed superconductivity. Conducting polymers are thus demonstrated to have the potential for the development of new superconducting technologies and devices.
@article{arxiv.1703.05803,
title = {Superconductivity in $p$-Terphenyl},
author = {Ren-Shu Wang and Yun Gao and Zhong-Bing Huang and Xiao-Jia Chen},
journal= {arXiv preprint arXiv:1703.05803},
year = {2017}
}