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Strongly Quenched Kramers Doublet Magnetism in SmMgAl11O19

Strongly Correlated Electrons 2026-01-21 v1 Materials Science

Abstract

We report magnetic susceptibility, isothermal magnetization, and specific-heat measurements on the rare-earth hexaaluminate SmMgAl11_{11}O19_{19}, where Sm3+^{3+} realizes a strongly quenched Kramers doublet on a triangular lattice with an exceptionally weak net exchange scale. The Curie--Weiss analysis yields strongly reduced ground-doublet gg factors, gab0.65g_{ab}\simeq 0.65 and gc0.70g_{c}\simeq 0.70. This indicates that the low-temperature response is governed primarily by single-ion physics, with crystal-field splitting and JJ-multiplet mixing jointly renormalizing the Sm3+^{3+} moment, rather than collective exchange. For HcH \parallel c, the specific heat shows no λ\lambda-type anomaly down to 0.35~K but evolves into a well-defined two-level Schottky peak whose gap grows linearly with field, yielding gc0.62g_c\simeq0.62 and recovering nearly all of Rln2R\ln2 at high fields, thereby confirming an effective Seff=12S_{\mathrm{eff}}=\tfrac12 Kramers doublet description for T10T\lesssim10~K. Together, these results establish SmMgAl11_{11}O19_{19} as a weak-exchange, nearly single-ion triangular Kramers magnet in which frustration produce an anisotropic low-field correlated regime without inducing long-range order.

Keywords

Cite

@article{arxiv.2601.13439,
  title  = {Strongly Quenched Kramers Doublet Magnetism in SmMgAl11O19},
  author = {Sonu Kumar and Barbora Salajová and Andrej Kancko and Cinthia A. Corrêa and Shuvajit Halder and Ross H. Colman},
  journal= {arXiv preprint arXiv:2601.13439},
  year   = {2026}
}