Saturn's moon Titan is the only extraterrestrial body known to host stable lakes and a hydrological cycle. Titan's lakes predominantly contain liquid methane, ethane, and nitrogen, with methane evaporation driving its hydrological cycle. Molecular interactions between these three species lead to non-ideal behavior that causes Titan's lakes to behave differently than Earth's lakes. Here, we numerically investigate how methane evaporation and non-ideal interactions affect the physical properties, structure, dynamics, and evolution of shallow lakes on Titan. We find that, under certain temperature regimes, methane-rich mixtures are denser than relatively ethane-rich mixtures. This allows methane evaporation to stratify Titan's lakes into ethane-rich upper layers and methane-rich lower layers, separated by a strong compositional gradient. At temperatures above 86K, lakes remain well-mixed and unstratified. Between 84 and 86K, lakes can stratify episodically. Below 84K, lakes permanently stratify, and develop very methane-depleted epilimnia. Despite small seasonal and diurnal deviations (<5K) from typical surface temperatures, Titan's rain-filled ephemeral lakes and "phantom lakes" may nevertheless experience significantly larger temperature fluctuations, resulting in polymictic or even meromictic stratification, which may trigger ethane ice precipitation.
@article{arxiv.2006.10896,
title = {Stratification Dynamics of Titan's Lakes via Methane Evaporation},
author = {Jordan K. Steckloff and Jason M. Soderblom and Kendra K. Farnsworth and Vincent F. Chevrier and Jennifer Hanley and Alejandro Soto and Jessica J. Groven and William M. Grundy and Logan A. Pearce and Stephen C. Tegler and Anna Engle},
journal= {arXiv preprint arXiv:2006.10896},
year = {2020}
}