Stochastic Simulation of Chemical Exchange in Two Dimensional Infrared Spectroscopy
Chemical Physics
2007-05-23 v1
Abstract
The stochastic Liouville equations are employed to investigate the combined signatures of chemical exchange (two-state-jump) and spectral diffusion (coupling to an overdamped Brownian oscillator) in the coherent response of an anharmonic vibration to three femtosecond infrared pulses. Simulations reproduce the main features recently observed in the OD stretch of phenol in benzene.
Keywords
Cite
@article{arxiv.physics/0603212,
title = {Stochastic Simulation of Chemical Exchange in Two Dimensional Infrared Spectroscopy},
author = {Frantisek Sanda and Shaul Mukamel},
journal= {arXiv preprint arXiv:physics/0603212},
year = {2007}
}
Comments
30 pages 8 figures