We study the online estimation of the optimal policy of a Markov decision process (MDP). We propose a class of Stochastic Primal-Dual (SPD) methods which exploit the inherent minimax duality of Bellman equations. The SPD methods update a few coordinates of the value and policy estimates as a new state transition is observed. These methods use small storage and has low computational complexity per iteration. The SPD methods find an absolute-ϵ-optimal policy, with high probability, using O((1−γ)6ϵ2∣S∣4∣A∣2σ2) iterations/samples for the infinite-horizon discounted-reward MDP and O(ϵ2∣S∣4∣A∣2H6σ2) for the finite-horizon MDP.