English

Statistics of multi-electron states and $J$-levels in atomic configurations

Atomic Physics 2025-09-10 v2

Abstract

The number and nature of atomic configurations are cornerstones of atomic spectroscopy, especially for the calculation of hot-plasma radiative properties. The knowledge of the distributions of magnetic quantum number MM and angular momentum JJ for NN identical fermions in a subshell with half-integer spin jj is a prerequisite to the determination of the structure of such configurations. The problem is rather complicated, since the possible occurrence of a specific values of JJ is governed by the Pauli exclusion principle. Several methods, such as generating functions, recurrence relations or algebraic number theory, for instance via Gaussian polynomials, have proven effective in addressing this issue. However, up to now, no general formula was known. In the present work, we present exact and compact explicit formulas for the number of atomic configurations and for the distributions of the total magnetic quantum number MM and angular momentum JJ.

Keywords

Cite

@article{arxiv.2509.04353,
  title  = {Statistics of multi-electron states and $J$-levels in atomic configurations},
  author = {Jean-Christophe Pain and Xavier Blanc},
  journal= {arXiv preprint arXiv:2509.04353},
  year   = {2025}
}

Comments

submitted to J. Phys. B: At. Mol. Opt. Phys