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Stabilizer Approximation II: From H$_2$O To C$_6$H$_6$

Quantum Physics 2023-02-24 v1 Strongly Correlated Electrons Atomic Physics Chemical Physics

Abstract

We apply the stabilizer method to the study of some complicated molecules, such as water and benzene. In the minimal STO-3G basis, the former requires 14 qubits, and the latter 72 qubits, which is very challenging. Quite remarkably, We are still able to find the best stabilizer states at all the bond lengths. Just as the previously studied H2_2, LiH and BeH2_2 molecules, here the stabilizer states also approximate the true ground states very well, especially when the molecules are strongly distorted. These results suggest stabilizer states could serve as natural reference states when the system involves strong static correlation. And in the language of quantum computing, one would expect stabilizer states to be natural initial states for chemical simulation.

Keywords

Cite

@article{arxiv.2302.11734,
  title  = {Stabilizer Approximation II: From H$_2$O To C$_6$H$_6$},
  author = {Jianan Wang and Chuixiong Wu and Fen Zuo},
  journal= {arXiv preprint arXiv:2302.11734},
  year   = {2023}
}

Comments

16 pages, 4 figures

R2 v1 2026-06-28T08:47:28.913Z