English

Spinodal-like scaling behavior after a temperature quench across the first-order phase transition in three-dimensional $q$-state Potts models

Statistical Mechanics 2026-05-21 v2

Abstract

We study the out-of-equilibrium spinodal-like behavior of three-dimensional (3D) qq-state Potts models (for q3q\ge 3), observed when the temperature is quenched across the first-order transition (FOT) point βfo=Tfo1\beta_{\rm fo}=T_{\rm fo}^{-1}. We consider a standard quench protocol, in which high-temperature configurations, thermalized at βi<βfo\beta_i<\beta_{\rm fo}, are driven across the FOT by a purely relaxational dynamics at β>βfo\beta>\beta_{\rm fo}. We focus on the emergence of spinodal-like behaviors in the thermodynamic limit, associated with the dynamic phase change. We argue that, if the nucleation of smooth droplets is the relevant mechanism of the post-quench phase change, for sufficiently small βfoβi>0\beta_{\rm fo}-\beta_i>0, the time-dependent energy density should scale in terms of ρ=(lnt)3/2δ\rho = (\ln t)^{3/2} \delta, where δ=β/βfo1\delta = \beta/\beta_{\rm fo}-1, with a discontinuity at a particular value ρ=ρs>0\rho=\rho_s>0. This implies the emergence of a spinodal-like behavior, whose time scale τ\tau increases exponentially as lnτ(ρs/δ)2/3\ln \tau \approx (\rho_s/\delta)^{2/3} in the limit δ0+\delta\to 0^+. We present a numerical analysis of the quench protocol in the 3D q=6q=6 Potts model, which supports the above spinodal-like scenario.

Keywords

Cite

@article{arxiv.2604.25351,
  title  = {Spinodal-like scaling behavior after a temperature quench across the first-order phase transition in three-dimensional $q$-state Potts models},
  author = {Andrea Pelissetto and Davide Rossini and Ettore Vicari},
  journal= {arXiv preprint arXiv:2604.25351},
  year   = {2026}
}

Comments

8 pages, 3 figures. Corrected misprints