English

Spinodal decomposition of a binary mixture in an uniform shear flow

Condensed Matter 2012-04-05 v1

Abstract

Results are presented for the phase separation process of a binary mixture subject to an uniform shear flow quenched from a disordered to a homogeneous ordered phase. The kinetics of the process is described in the context of the time-dependent Ginzburg-Landau equation with an external velocity term. The one-loop approximation is used to study the evolution of the model. We show that the structure factor obeys a generalized dynamical scaling. The domains grow with different typical lengthscales RxR_x and RyR_y respectively in the flow and in the shear directions. In the scaling regime RytαyR_y \sim t^{\alpha_y} and RxtαxR_x \sim t^{\alpha_x}, with αx=5/4\alpha_x=5/4 and αy=1/4\alpha_y =1/4. The excess viscosity Δη\Delta \eta after reaching a maximum relaxes to zero as γ2t3/2\gamma ^{-2}t^{-3/2}, γ\gamma being the shear rate. Δη\Delta \eta and other observables exhibit log-time periodic oscillations which can be interpreted as due to a growth mechanism where stretching and break-up of domains cyclically occur.

Keywords

Cite

@article{arxiv.cond-mat/9806239,
  title  = {Spinodal decomposition of a binary mixture in an uniform shear flow},
  author = {F. Corberi and G. Gonnella and A. Lamura},
  journal= {arXiv preprint arXiv:cond-mat/9806239},
  year   = {2012}
}

Comments

4 Revtex pages, 3 figures