We have studied the nature and dynamics of spin-dependent charge carrier recombination in Tris(8-hydroxyquinolinato) aluminum (Alq3) films in light emitting diodes at room temperature using continuous wave and pulsed electrically detected magnetic resonance (EDMR) spectroscopy. We found that the EDMR signal is dominated by an electron-hole recombination process, and another, weaker EDMR signal whose fundamental nature was investigated. From the pulsed EDMR measurements we obtained a carrier spin relaxation time, T2=45±25 ns which is much shorter than T2 in conjugated polymers, but relatively long for a molecule containing elements with high atomic number. Using multi-frequency continuous wave EDMR spectroscopy, we obtained the local hyperfine field distributions for electrons and holes, as well as their respective spin-orbit coupling induced g-factor and g-strain values.
@article{arxiv.2004.00765,
title = {Spin-Dependent Charge-Carrier Recombination Processes in Tris(8-Hydroxyquinolinato) Aluminum},
author = {H. Popli and X. Liu and T. H. Tennahewa and M. Y. Teferi and E. Lafalce and H. Malissa and Z. V. Vardeny and C. Boehme},
journal= {arXiv preprint arXiv:2004.00765},
year = {2020}
}