Precise low-frequency light scattering experiments on silica glass are presented, covering a broad temperature and frequency range (9 GHz < \nu < 2 THz). For the first time the spectral shape of relaxations is observed over more than one decade in frequency. The spectra show a power-law low-frequency wing of the relaxational part of the spectrum with an exponent α proportional to temperature in the range 30 K < T < 200 K. A comparison of our results with those from acoustic attenuation experiments performed at different frequencies shows that this power-law behaviour rather well describes relaxations in silica over 9 orders of magnitude in frequency. These findings can be explained by a model of thermally activated transitions in double well potentials.
@article{arxiv.cond-mat/9910347,
title = {Spectral Shape of Relaxations in Silica Glass},
author = {Johannes Wiedersich and Sergei V. Adichtchev and Ernst R"ossler},
journal= {arXiv preprint arXiv:cond-mat/9910347},
year = {2009}
}