We present density functional theory calculations for low-Tc metallic ferromagnet La5Co2Ge3 at ambient and applied pressures. Our investigations reveal that the system is a quasi-one-dimensional ferromagnet with a peculiar coexistence of two different orbital-selective magnetic moments at two crystallographically inequivalent cobalt atoms, Co1 and Co2. Namely, due to different crystal-field splitting, the magnetic moment of Co1 atoms predominantly derives from dxz orbital whereas of Co2 atoms from dxy orbital. Consequently, Co1 and Co2 atoms develop unequal net magnetic moments, a feature that gives rise to a periodic, spatial modulation of magnetization along crystallographic c-direction. The amplitude of the spatial modulation, small at ambient pressure, drastically increases with applied pressure, until Co2 atoms become nonmagnetic. With the help of a toy model mimicking found orbital-selective ferromagnetic order, we demonstrate that the increasing amplitude of spatial modulation provides a consistent interpretation to the recently observed resistivity anomaly emerging at applied pressure identified as the appearance of the {\it new state}. Although, proposed here structural origin of the spatial modulation of magnetic moments in La5Co2Ge3 is an alternative one to the advocated for this material ferromagnetic quantum criticality avoidance, the effects of quantum fluctuations can still play an important role at pressure larger than up-to-date measured 5GPa.
@article{arxiv.2104.04245,
title = {Spatially modulated, orbital selective ferromagnetism in La$_5$Co$_2$Ge$_3$},
author = {Giuseppe Cuono and Carmine Autieri and Marcin M. Wysokiński},
journal= {arXiv preprint arXiv:2104.04245},
year = {2026}
}