English

Spatial dispersion in CaF$_2$ caused by the vicinity of an excitonic bound state

Strongly Correlated Electrons 2015-06-24 v1 Materials Science

Abstract

The microscopic mechanism beyond the optical anisotropy of an ionic crystal which occurs for short wavelengths is investigated. The electron-hole, two particle propagator and its analytical behaviour close to the band edge of the one particle continuum plays a major role for the mechanism of this optical anisotropy. Especially for an ionic crystal the two particle bound state, the exciton, is of special importance. In this way we argue that the so called ``intrinsic birefringence'' in CaF2_2 is neither intrinsic to the material nor it is birefringence. Instead it is spatial dispersion caused by the vicinity of a dispersive optical absorption given by the excitonic bound state. We propose a model which connects the bound state dispersion with the band structure and a model potential for a screened coulomb interaction. Based on these considerations we predict a wavelength dependence of the dielectric function approaching close to the bound state level ϵ(λλ0)1\epsilon \sim (\lambda - \lambda_0)^{-1}, where λ0\lambda_0 is the wavelength of the excitonic bound state level.

Keywords

Cite

@article{arxiv.cond-mat/0204282,
  title  = {Spatial dispersion in CaF$_2$ caused by the vicinity of an excitonic bound state},
  author = {M. Letz and W. Mannstadt and M. Brinkmann and E. Moersen},
  journal= {arXiv preprint arXiv:cond-mat/0204282},
  year   = {2015}
}

Comments

7 pages, 3 figures, to appear in SPIE proceedings of microlithography 2002