Size consistent excited states via algorithmic transformations between variational principles
Chemical Physics
2017-09-01 v1
Abstract
We demonstrate that a broad class of excited state variational principles is not size consistent. In light of this difficulty, we develop and test an approach to excited state optimization that transforms between variational principles in order to achieve state selectivity, size consistency, and compatibility with quantum Monte Carlo. To complement our formal analysis, we provide numerical examples that confirm these properties and demonstrate how they contribute to a more black box approach to excited states in quantum Monte Carlo.
Keywords
Cite
@article{arxiv.1708.09805,
title = {Size consistent excited states via algorithmic transformations between variational principles},
author = {Jacqueline A. R. Shea and Eric Neuscamman},
journal= {arXiv preprint arXiv:1708.09805},
year = {2017}
}
Comments
27 pages, 10 figures, 2 tables