A simple theoretical model is developed to describe spin reorientation (SR) transitions in rare-earth orthoferrites and orthochromites RFeO3 and RCrO3. Within a ``single-doublet'' approach, the free energy includes anisotropy contributions from the 3d-sublattice and the splitting of the lower doublet of 4f-ions. The model predicts various types of SR transitions - first-order, second-order, and mixed - depending on anisotropy parameters. Effects of non-magnetic dilution, heat capacity anomalies, and behavior of the rare-earth magnetic moment in the SR region are analyzed.
@article{arxiv.2512.14771,
title = {Single-doublet model of spin reorientation},
author = {Evgenii Vasinovich and Alexander Moskvin},
journal= {arXiv preprint arXiv:2512.14771},
year = {2025}
}