We present observations of highly frustrated quasi two-dimensional (2D) magnetic correlations in the honeycomb lattice layers of the Seff = 1/2 compound γ-BaCo2(PO4)2 (γ-BCPO). Specific heat shows a broad peak comprised of two weak kink features at TN1∼ 6 K and TN2∼ 3.5 K, the relative weights of which can be modified by sample annealing. Neutron powder diffraction measurements reveal short range quasi-2D order that is established below TN1 and TN2, at which two separate, incompatible, short range magnetic orders onset: commensurate antiferromagnetic correlations with correlation length ξc=60±2 \AA \ (TN1) and in quasi-2D helical domains with ξh=350±11 \AA \ (TN2). The ac magnetic susceptibility response lacks frequency dependence, ruling out spin freezing. Inelastic neutron scattering data on γ-BCPO is compared with linear spin wave theory, and two separate parameter regions of the XXZ J1-J2-J3 model with ferromagnetic nearest-neighbor exchange J1 are favored, both near regions of high classical degeneracy. High energy coherent excitations (∼10 meV) persist up to at least 40 K, suggesting strong in-plane correlations persist above TN. These data show that γ-BCPO is a rare highly frustrated, quasi-2D Seff = 1/2 honeycomb lattice material which resists long range magnetic order and spin freezing.
@article{arxiv.1712.06208,
title = {Short range order in the quantum XXZ honeycomb lattice material BaCo$_2$(PO$_4$)$_2$},
author = {H. S. Nair and J. M. Brown and E. Coldren and G. Hester and M. P. Gelfand and A. Podlesnyak and Q. Huang and K. A. Ross},
journal= {arXiv preprint arXiv:1712.06208},
year = {2018}
}