English

Short range order in the quantum XXZ honeycomb lattice material BaCo$_2$(PO$_4$)$_2$

Strongly Correlated Electrons 2018-04-18 v2

Abstract

We present observations of highly frustrated quasi two-dimensional (2D) magnetic correlations in the honeycomb lattice layers of the Seff_{eff} = 1/2 compound γ\gamma-BaCo2_2(PO4_4)2_2 (γ\gamma-BCPO). Specific heat shows a broad peak comprised of two weak kink features at TN1T_{N1} \sim 6 K and TN2T_{N2} \sim 3.5 K, the relative weights of which can be modified by sample annealing. Neutron powder diffraction measurements reveal short range quasi-2D order that is established below TN1T_{N1} and TN2T_{N2}, at which two separate, incompatible, short range magnetic orders onset: commensurate antiferromagnetic correlations with correlation length ξc=60±2\xi_c = 60\pm2 \AA \ (TN1T_{N1}) and in quasi-2D helical domains with ξh=350±11\xi_h = 350 \pm 11 \AA \ (TN2T_{N2}). The ac magnetic susceptibility response lacks frequency dependence, ruling out spin freezing. Inelastic neutron scattering data on γ\gamma-BCPO is compared with linear spin wave theory, and two separate parameter regions of the XXZ J1J_1-J2J_2-J3J_3 model with ferromagnetic nearest-neighbor exchange J1J_1 are favored, both near regions of high classical degeneracy. High energy coherent excitations (10\sim 10 meV) persist up to at least 40 K, suggesting strong in-plane correlations persist above TNT_N. These data show that γ\gamma-BCPO is a rare highly frustrated, quasi-2D Seff_{eff} = 1/2 honeycomb lattice material which resists long range magnetic order and spin freezing.

Keywords

Cite

@article{arxiv.1712.06208,
  title  = {Short range order in the quantum XXZ honeycomb lattice material BaCo$_2$(PO$_4$)$_2$},
  author = {H. S. Nair and J. M. Brown and E. Coldren and G. Hester and M. P. Gelfand and A. Podlesnyak and Q. Huang and K. A. Ross},
  journal= {arXiv preprint arXiv:1712.06208},
  year   = {2018}
}

Comments

9 pages, 12 figures