English

Short-Range Correlations in Magnetite above the Verwey Temperature

Strongly Correlated Electrons 2014-03-19 v1 Materials Science

Abstract

Magnetite, Fe3_3O4_4, is the first magnetic material discovered and utilized by mankind in Ancient Greece, yet it still attracts attention due to its puzzling properties. This is largely due to the quest for a full and coherent understanding of the Verwey transition that occurs at TV=124T_V=124 K and is associated with a drop of electric conductivity and a complex structural phase transition. A recent detailed analysis of the structure, based on single crystal diffraction, suggests that the electron localization pattern contains linear three-Fe-site units, the so-called trimerons. Here we show that whatever the electron localization pattern is, it partially survives up to room temperature as short-range correlations in the high-temperature cubic phase, easily discernible by diffuse scattering. Additionally, {\it ab initio} electronic structure calculations reveal that characteristic features in these diffuse scattering patterns can be correlated with the Fermi surface topology.

Keywords

Cite

@article{arxiv.1401.4091,
  title  = {Short-Range Correlations in Magnetite above the Verwey Temperature},
  author = {Alexey Bosak and Dmitry Chernyshov and Moritz Hoesch and Przemyslaw Piekarz and Mathieu Le Tacon and Michael Krisch and Andrzej Kozlowski and Andrzej M. Oleś and Krzysztof Parlinski},
  journal= {arXiv preprint arXiv:1401.4091},
  year   = {2014}
}

Comments

7 pages, 6 figures

R2 v1 2026-06-22T02:47:33.541Z