English

Shear Flows and Segregation in the Reaction $A+B\to\emptyset$

Condensed Matter 2009-10-28 v1

Abstract

We study theoretically and numerically the effects of the linear velocity field v=v0yx^{\bf v}=v_0y{\bf\hat x} on the irreversible reaction A+BA+B\rightarrow\emptyset. Assuming homogeneous initial conditions for the two species, with equal initial densities, we demonstrate the presence of a crossover time tcv01t_c\sim v_0^{-1}. For tv01t\ll v_0^{-1}, the kinetics are unaffected by the shear and we retain both the effect of species segregation (for d<4d<4) and the density decay rate AtαAt^{-\alpha}, where α=min(d4,1)\alpha=\min({d\over 4},1). We calculate the amplitude AA to leading order in a small density expansion for 2d<42\leq d<4, and give bounds in d=4d=4. However, for tv01t\gg v_0^{-1}, the critical dimension for anomalous kinetics is reduced to dc=2d_c=2, with the density decay rate Bt1Bt^{-1} holding for d2d\geq 2. Bounds are calculated for the amplitude BB in d=2d=2, which depend on the velocity gradient v0v_0 and the (equal) diffusion constants DD. We also briefly consider the case of a non-linear shear flow, where we give a more general form for the crossover time tct_c. Finally, we perform numerical simulations for a linear shear flow in d=2d=2 with results in agreement with theoretical predictions.

Keywords

Cite

@article{arxiv.cond-mat/9601098,
  title  = {Shear Flows and Segregation in the Reaction $A+B\to\emptyset$},
  author = {M. J. Howard and G. T. Barkema},
  journal= {arXiv preprint arXiv:cond-mat/9601098},
  year   = {2009}
}

Comments

26 pages latex document, 13 figures, uses epsf.sty