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Self-consistent GW theory for superconductivity in SrTiO3 models

Superconductivity 2026-07-21 v1 Materials Science Strongly Correlated Electrons Chemical Physics

Abstract

Superconductivity in doped SrTiO3_3 occurs over a wide range of carrier densities, including those for which the Fermi energy is below the polar longitudinal optical phonon scale. In this regime, the assumptions underpinning conventional implementations of Migdal-Eliashberg theory, including frequency cutoffs at the phonon scale and a Coulomb pseudopotential μ\mu^\ast, are not valid. We solve the finite-temperature GWGW equations with full momentum and frequency dependence, without cutoffs or μ\mu^\ast, for polar one-band models of SrTiO3_3, using effective masses and three-phonon dielectric functions parameterized from ab initio calculations. Comparing different self-consistency levels, namely G0W0G_0W_0, GW0GW_0, and fully self-consistent GWGW, we find that the one-shot (G0W0G_0W_0) kernel overestimates the pairing-onset temperature by one to two orders of magnitude. The dominant suppression comes from replacing G0G_0 by GG, thereby incorporating the phonon renormalization factor in the electron Green function. Using the self-consistently computed interaction WW further lowers and narrows the pairing-onset dome. In the dilute limit, our calculations identify the pairing channel as the Fr\"ohlich phonon interaction screened by the incipient ferroelectricity of the material, with plasmonic and electronic screening effects negligible. The numerical solution of the full equations reveals a pairing-onset scale that remains non-zero as the density tends to zero, whereas Fermi-surface projection or Fermi-energy frequency truncation removes it. This work highlights the relevance of incipient ferroelectricity, the importance of self-consistency, and the need for a full momentum- and frequency-dependent treatment in modeling superconductivity in SrTiO3_3-like doped polar semiconductors.

Cite

@article{arxiv.2607.18757,
  title  = {Self-consistent GW theory for superconductivity in SrTiO3 models},
  author = {Zhi-Hao Cui and John Sous and Andrew J. Millis and David R. Reichman},
  journal= {arXiv preprint arXiv:2607.18757},
  year   = {2026}
}

Comments

18 pages, 8 figures