Scott correction for large atoms and molecules in a self-generated magnetic field
Mathematical Physics
2015-05-28 v1 math.MP
Abstract
We consider a large neutral molecule with total nuclear charge in non-relativistic quantum mechanics with a self-generated classical electromagnetic field. To ensure stability, we assume that for a sufficiently small , where denotes the fine structure constant. We show that, in the simultaneous limit , such that is fixed, the ground state energy of the system is given by a two term expansion . The leading term is given by the non-magnetic Thomas-Fermi theory. Our result shows that the magnetic field affects only the second (so-called Scott) term in the expansion.
Keywords
Cite
@article{arxiv.1105.0521,
title = {Scott correction for large atoms and molecules in a self-generated magnetic field},
author = {Laszlo Erdos and Soren Fournais and Jan Philip Solovej},
journal= {arXiv preprint arXiv:1105.0521},
year = {2015}
}