Rules for transition rates in nonequilibrium steady states
Statistical Mechanics
2009-11-10 v1
Abstract
Just as transition rates in a canonical ensemble must respect the principle of detailed balance, constraints exist on transition rates in driven steady states. I derive those constraints, by maximum information-entropy inference, and apply them to the steady states of driven diffusion and a sheared lattice fluid. The resulting ensemble can potentially explain nonequilibrium phase behaviour and, for steady shear, gives rise to stress-mediated long-range interactions.
Keywords
Cite
@article{arxiv.cond-mat/0402527,
title = {Rules for transition rates in nonequilibrium steady states},
author = {R. M. L. Evans},
journal= {arXiv preprint arXiv:cond-mat/0402527},
year = {2009}
}
Comments
4 pages. To appear in Physical Review Letters